A capability map describes what the organisation needs to be able to do, expressed independently of how it is done today. It is stable across reorganisations, leadership changes, and platform decisions.
A target architecture describes how those capabilities will be delivered: the platforms, patterns, and ownership boundaries that will carry them. It is specific, dated to the version of the system it describes, and revisable when the evidence changes.
In practice the map comes first and constrains the target. A target architecture written against a fuzzy capability list becomes a guess about which platforms serve which outcomes.